報告題目:MoC基催化劑上的水汽變換反應
報告人:馬 丁 教授
報告時間:2021年10月16日上午10:30
報告地點:化學樓2樓1號會議室
報告摘要:
In the early studies of heterogeneous catalytic applications of transition metal carbides (TMCs), the carbide itself was used individually as the catalytic active site which exhibited unique catalytic performance comparable to precious metal catalysts towards hydrogenation, dehydrogenation, isomerization, and hydrodeoxygenation. To promote the catalytic performance, the doping of secondary transition metals into the carbide lattice to form bimetallic carbides was extensively studied. In a third approach, TMCs could be used with noble metal or other transition metals, constituting the bifunctional or interfacial catalyst system. Indeed, due to its unique nature of chemical structures and electronic properties, molybdenum carbide has exhibited tremendous advantages as a promising catalyst and support for metal catalysts, leading to improved activity, selectivity and stability of catalysts. In this talk, recent progress has been reviewed for the preparation and rational design of molybdenum carbide-based catalysts towards reactions such as hydrogen production and purification, CO-resistant hydrogenation and tandem bifunctional conversion of CO+H2O in biomass conversion and FTS. The understandings toward the structure-performance relationship in molybdenum carbide and molybdenum carbide supported catalysts are also addressed.
報告人簡介:
馬丁,北京大學化學與分子工程學院教授。針對我國社會能源和資源優化利用過程,主要開展氫能制備與輸運,以及高值碳基化學品/油品合成, 以及催化反應機理研究等方面研究工作。獲得2013年度北京大學青年教師教學比賽一等獎,2017年度中國科學十大進展,2018年度北京大學十佳導師。